POLYMER COMPLEXES STABILIZED THROUGH HYDROGEN-BONDS - A SEMIQUANTITATIVE THEORETICAL-MODEL

被引：22

作者：

ILIOPOULOS, I

AUDEBERT, R

机构：

[1] CNRS, France

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1988年 / 26卷 / 10期

关键词：

Acids--Organic; -; Acrylics--Chemistry;

D O I：

10.1002/polb.1988.090261006

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The authors develop a semiquantitative theoretical model for cooperative association between macromolecules. The model is especially adapted for reversible polymer complexes stabilized through weak interactions, e.g., through hydrogen bonds. Theoretical predictions are compared with potentiometric and viscometric experimental results of poly(acrylic acid)/poly-base system and a good agreement is established. The influence of parameters such as degree of neutralization of the polyacid, concentration, and molecular weight of polymers is also predicted.

引用

页码：2093 / 2112

页数：20

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