POTASSIUM SELECTIVE CHROMOIONOPHORES

被引：7

作者：

DANKS, IP ^{[1
]}

SUTHERLAND, IO ^{[1
]}

机构：

[1] UNIV LIVERPOOL, DEPT CHEM, POB 147, LIVERPOOL L69 3BX, ENGLAND

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1992年 / 12卷 / 1-4期

关键词：

CHROMOIONOPHORES; POTASSIUM; HEMISPHERAND; OPTICAL FIBER SENSORS;

D O I：

10.1007/BF01053864

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ionisable chromoionophores 5 were synthesised from simple precursors. These chromoionophores extract alkali metal cations from aqueous solutions at pH > 7 into dichloromethane. The ratio of extraction coefficients for the chromoionophore 5c for K+ and Na+ indicate that it has potential for use in optical fibre sensors for K+ in the presence of Na+, Mg2+, and Ca2+ at extracellular concentrations.

引用

页码：223 / 236

页数：14

共 54 条

[1] AN OPTICAL POTASSIUM-ION SENSOR [J].

ALDER, JF ;

ASHWORTH, DC ;

NARAYANASWAMY, R ;

MOSS, RE ;

SUTHERLAND, IO .

ANALYST, 1987, 112 (08) :1191-1192

[2]

ARTZ SP, 1984, J AM CHEM SOC, V106, P2160, DOI 10.1021/ja00319a042

[3] SPHERANDS CONTAINING CYCLIC UREA UNITS [J].

BRYANT, JA ;

HO, SP ;

KNOBLER, CB ;

CRAM, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (15) :5837-5843

[4] HOST GUEST COMPLEXATION .53. FUNCTIONAL-GROUPS PREORGANIZED IN HEMISPHERANDS FOR BINDING ALKALI-METAL AND AMMONIUM CATIONS [J].

BRYANT, JA ;

HELGESON, RC ;

KNOBLER, CB ;

DEGRANDPRE, MP ;

CRAM, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (15) :4622-4634

[5]

COREY EJ, 1976, TETRAHEDRON LETT, P809

[6]

COREY EJ, 1972, TETRAHEDRON LETT, P4339

[7] HOST-GUEST COMPLEXATION .45. A HIGHLY PREORGANIZED CHROMOGENIC SPHERAND INDICATOR SYSTEM SPECIFIC FOR SODIUM AND LITHIUM IONS [J].

CRAM, DJ ;

CARMACK, RA ;

HELGESON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (02) :571-577

[8] THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE) [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1009-1020

[9]

CRAM DJ, 1981, TOP CURR CHEM, V98, P43

[10] PREORGANIZATION - FROM SOLVENTS TO SPHERANDS [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (12) :1039-1057

← 1 2 3 4 5 6 →