RING-OPENING METATHESIS POLYMERIZATION OF DICYCLOPENTADIENE BY UNICOMPONENT CATALYSTS DERIVED FROM WCL6

被引：14

作者：

BALCAR, H

DOSEDLOVA, A

PETRUSOVA, L

机构：

[1] J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 182 23 Prague, Dolejskova 3

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 77卷 / 03期

关键词：

D O I：

10.1016/0304-5102(92)80208-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The complexes WCl5(OR), where R=-CH-(CH2Cl)2 or substituted phenyl, and WOCl4 have been found to initiate ring-opening metathesis polymerization of dicyclopentadiene without any co-catalyst. Their activities are, however, lower than when they are associated with a reducing organometallic co-catalyst. The unicomponent catalysts afford a slightly crosslinked, partially soluble polymer with a relatively high content of cis double bonds in the main chain.

引用

页码：289 / 295

页数：7

共 10 条

[1] APPLICATIONS OF CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN IN OLEFIN METATHESIS - THE RING-OPENING METATHESIS POLYMERIZATION OF DICYCLOPENTADIENE [J].

BOUTARFA, D ;

PAILLET, C ;

LECONTE, M ;

BASSET, JM .

JOURNAL OF MOLECULAR CATALYSIS, 1991, 69 (02) :157-169

[2] TUNGSTEN PHENOXIDES AS METATHESIS CATALYSTS [J].

DODD, HT ;

RUTT, KJ .

JOURNAL OF MOLECULAR CATALYSIS, 1982, 15 (1-2) :103-110

[3]

GUNTHER P, 1970, ANGEW MAKROMOL CHEM, V14, P87

[4] STRUCTURAL SEQUENCES IN RING-OPENED POLYMERS AND CO-POLYMERS OF CYCLOALKENES AS A GUIDE TO THE MECHANISM OF OLEFIN METATHESIS [J].

IVIN, KJ ;

LAPIENIS, G ;

ROONEY, JJ ;

STEWART, CD .

JOURNAL OF MOLECULAR CATALYSIS, 1980, 8 (1-3) :203-218

[5]

IVIN KJ, 1983, OLEFIN METATHESIS, P259

[6] MECHANISM OF INITIATION OF RING-OPENING POLYMERIZATION OF NORBORNENE CATALYZED BY TRANSITION-METAL HALIDES [J].

LAVERTY, DT ;

MCKERVEY, MA ;

ROONEY, JJ ;

STEWART, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (06) :193-194

[7] RING-OPENING POLYMERIZATION OF NORBORNENE AND ITS DERIVATIVES BY MOCL5 WCL6 AND RECL5 CATALYSTS [J].

OSHIKA, T ;

TABUCHI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (01) :211-+

[8] ARYLOXIDE LIGANDS IN METATHESIS OF OLEFINS AND OLEFINIC ESTERS - CATALYTIC BEHAVIOR OF W(OAR)2CL4 COMPLEXES ASSOCIATED WITH ALKYL-TIN OR ALKYL-LEAD COCATALYSTS - ALKYLATION OF W(OAR)2CL4 BY SNME4, SN(N-BU)4, PB(N-BU)4, MGNP2 - SYNTHESIS OF W(OAR)2CL2(CHCME3)(OR2) AND W(OAR)2CL(CHCME3)(CH2CME3)(OR2) [J].

QUIGNARD, F ;

LECONTE, M ;

BASSET, JM .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 36 (1-2) :13-29

[9] ARYLOXIDE LIGANDS IN THE METATHESIS OF OLEFINS - SYNTHESES OF W(OAR)XCL6-X COMPLEXES WITH X = 2, 3, AND 4 - CRYSTAL-STRUCTURES OF W(O-2,6-C6H3-I-PR2)3CL3 AND W(O-2,6-C6H3PH2)2CL4 [J].

QUIGNARD, F ;

LECONTE, M ;

BASSET, JM ;

HSU, LY ;

ALEXANDER, JJ ;

SHORE, SG .

INORGANIC CHEMISTRY, 1987, 26 (25) :4272-4277

[10]

1965, Patent No. 181641

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