VIBRATIONAL SPECTRUM OF CRYSTALLINE METHANETHIOL

被引:8
作者
MAY, IW
PACE, EL
机构
[1] Department of Chemistry, Case Western Reserve Uuniversity, Cleveland
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 12期
基金
美国国家科学基金会;
关键词
D O I
10.1016/0584-8539(69)80221-7
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The infrared spectra of the two phases of CH3SH and CH3SD have been studied at 80 °K. A powder X-ray pattern of the supercooled high temperature phase obtained at liquid nitrogen temperature indicates that the unit cell is primitive ortho-rhombic and that it contains eight molecules. Analysis of the factor group splittings of this phase and other structural data favors either D2h1(Pmmm) or D2h5(Pmma) space groups. © 1969.
引用
收藏
页码:1903 / &
相关论文
共 8 条
[1]  
AZAROFF LV, 1958, POWDER METHOD, P84
[2]  
COTTON FA, 1962, ADV INORG CHEM, P104
[3]  
DOWS DA, 1936, PHYSICS CHEMISTRY OR, V1, P585
[4]  
HOCHSTRASSER RM, 1966, MOLECULAR ASPECTS SY, P308
[5]   VIBRATIONAL SPECTRA OF METHANETHIOL [J].
MAY, IW ;
PACE, EL .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1968, A 24 (10) :1605-+
[6]   INFRARED SPECTRA OF ACETONITRILE AND ACETONITRILE-D3 [J].
PACE, EL ;
NOE, LJ .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (12) :5317-&
[7]   The heat capacity, entropy, heats of fusion, transition, and vaporization and vapor pressures of methyl mercaptan [J].
Russell, H ;
Osborne, DW ;
Yost, DM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :165-169
[8]  
1952, INT TABLES XRAY CRYS, V1