SOLID-STATE PT-195 NMR-STUDIES OF THE COMPLEXES PT(EN)CLX (EN = 1,2-DIAMINOETHANE X = 2,3 OR 4)

被引：16

作者：

AUSTIN, EJW ^{[1
]}

BARRIE, PJ ^{[1
]}

CLARK, RJH ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001404

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pt-195 magic-angle spinning (MAS) NMR spectra of the monomeric complexes Pt(en)Cl2 and Pt(en)Cl4 and of the linear-chain complex [Pt(en)Cl2][Pt(en)Cl4] show that the Pt(II) and Pt(IV) sites in the mixed-valence complex have isotropic chemical shifts and shielding anisotropies that are surprisingly similar to those of their monomeric constituents.

引用

页码：1404 / 1405

页数：2

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