FORMYL-ENDED HETEROBIFUNCTIONAL POLY(ETHYLENE OXIDE) - SYNTHESIS OF POLY(ETHYLENE OXIDE) WITH A FORMYL GROUP AT ONE END AND A HYDROXYL GROUP AT THE OTHER END

被引：87

作者：

NAGASAKI, Y ^{[1
]}

KUTSUNA, T ^{[1
]}

IIJIMA, M ^{[1
]}

KATO, M ^{[1
]}

KATAOKA, K ^{[1
]}

KITANO, S ^{[1
]}

KADOMA, Y ^{[1
]}

机构：

[1] NIPPON OIL & FATS CO LTD,TSUKUBA RES LAB,TSUKUBA,IBARAKI 30026,JAPAN

来源：

BIOCONJUGATE CHEMISTRY | 1995年 / 6卷 / 02期

关键词：

D O I：

10.1021/bc00032a012

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Well-defined poly(ethylene oxide) (PEG) with a formyl group at one end and a hydroxyl group at the other terminus was synthesized by the anionic ring opening polymerization of ethylene oxide (EO) with a new organometallic initiator possessing an acetal moiety, potassium 3,3-diethoxypropyl alkoxide. Hydrolysis of the acetal moiety produced a formyl group-terminated heterobifunctional PEO with a hydroxyl group at the other end.

引用

页码：231 / 233

页数：3

共 15 条

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