RADICAL RING-OPENING POLYMERIZATION BEHAVIOR OF VINYLCYCLOPROPANES DERIVED FROM DIENES AND CHLOROFORM

被引：29

作者：

ENDO, T

SUGA, K

机构：

[1] Tokyo Inst of Technology, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1989年 / 27卷 / 06期

关键词：

Catalysts--Selectivity - Chlorine Compounds--Chemical Reactions - Olefins--Isomerization - Polymerization--Reaction Kinetics;

D O I：

10.1002/pola.1989.080270604

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

1,1-Dichloro-2-vinylcyclopropane (Ia), 1,1-dichloro-2-methyl-2-vinylcyclopropane (Ib), 1,1,2-trichloro-2-vinylcyclopropane (Ic) were prepared from the corresponding dienes and chloroform in the presence of a phase transfer catalyst (PTC), R4N+Cl-. Monomers Ia-Ic underwent a clean 1,5-type radical ring-opening process to afford the corresponding polymers in good yield. Further, the relative rate of polymerization and reaction of (I) with thiophenol were studied.

引用

页码：1831 / 1842

页数：12

共 14 条

[1]

BOVEY FA, 1972, HIGH RESOLUTION NMR, P219

[2] POLYMERIZATIONS OF SUBSTITUTED CYCLOPROPANES .1. RADICAL POLYMERIZATION OF 1,1-DISUBSTITUTED 2-VINYLCYCLOPROPANES [J].