DABCO-CATALYZED DIMERIZATION OF SOME ALPHA,BETA-UNSATURATED ESTERS

被引：40

作者：

DREWES, SE

EMSLIE, ND

KARODIA, N

机构：

[1] Department of Chemistry, University of Natal, 375

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 13期

关键词：

D O I：

10.1080/00397919008053121

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acrylate esters readily undergo the Baylis-Hi1lman reaction with aldehydes in the presence of DABCO. In the absence of aldehydes it has now been established that esters with good leaving groups undergo self condensation (Michael addition) to afford dimers in almost quantitative yield. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1915 / 1921

页数：7

共 9 条

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