BEHAVIOR OF NITRILE OXIDES TOWARDS NUCLEOPHILES .5. POLYMERIZATION OF AROMATIC NITRILE OXIDES

被引：5

作者：

DESARLO, F

GUARNA, A

机构：

[1] Centro di Studio sulla Chimica e la Struttura dei Composti Eterociclici e Loro Applicazioni, C.N.R., Università di Firenze

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 11期

关键词：

D O I：

10.1039/p19790002793

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic nitrile oxides undergo polymerization by treatment with trimethylamine in dimethyl sulphoxide. Chain lengthening occurs via the C-O bonds, as shown by the catalytic hydrogenation of such polymers to aroylamides. The apparent degree of polymerization ranges from 15 up to ca. 100 monomer units. These polymers are quite stable in the solid state, but slowly decompose in solution; they do not give the typical reactions of nitrile oxides.

引用

页码：2793 / 2794

页数：2

共 7 条

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