AZARHODA-CLOSO-DODECABORANE

被引：19

作者：

HANSEN, HP ^{[1
]}

MULLER, J ^{[1
]}

ENGLERT, U ^{[1
]}

PAETZOLD, P ^{[1
]}

机构：

[1] TH DARMSTADT,INST ANORGAN CHEM,TEMPLERGRABEN 55,W-6100 DARMSTADT,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A distorted RhNB10 icosahedron containing a six-fold coordinated N atom forms the basic structure of the complex [{Ph3P)2RhH}NB10H11] (1, depicted to the right without the PPh3 substituents), which is accessible from the anion nido-NB10H12- and [(Ph3P)3RhCl]. The open pentagonal side of the anion becomes a pentahapto ligand and the bridging H atoms migrate to rhodium.

引用

页码：1377 / 1379

页数：3

共 10 条

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