SAMARIUM DIIODIDE-INDUCED REDUCTION OF ELEMENTAL SELENIUM LEADING TO A SELENOLATE ANION SPECIES - A SELECTIVE SYNTHESIS OF DIACYL DISELENIDES

被引：6

作者：

JIA, XS ^{[1
]}

ZHANG, YM ^{[1
]}

ZHOU, XJ ^{[1
]}

机构：

[1] HANGZHOU UNIV,DEPT CHEM,HANGZHOU 310028,PEOPLES R CHINA

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 10期

关键词：

D O I：

10.1080/00397919308011229

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Elemental selenium was reduced by samarium diiodide in THF to produce selenolate anion species which reacted with acyl chlorides to give diacyl diselenides in good yields under mild and neutral conditions.

引用

页码：1403 / 1408

页数：6

共 11 条

[1] SYNTHESIS AND PROPERTIES OF DIACYL SELENIDES [J].

ISHIHARA, H ;

SATO, S ;

HIRABAYASHI, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1977, 50 (11) :3007-3009

[2] ORGANIC SELENIUM-COMPOUNDS .18. ON EXISTENCE OF MONOSELENOCARBOXYLIC ACIDS [J].

JENSEN, KA ;

BOJE, L ;

HENRIKSE.L .

ACTA CHEMICA SCANDINAVICA, 1972, 26 (04) :1465-&

[3]

JOHN AS, 1991, ALDRICHIM ACTA, V1, P15

[4] REDUCTION USING SAMARIUM DIIODIDE-BASE SYSTEM [J].

KAMOCHI, Y ;

KUDO, T .

TETRAHEDRON LETTERS, 1991, 32 (29) :3511-3514

[5] CONTROLLED REDUCTION OF NITROALKANES TO ALKYL HYDROXYLAMINES OR AMINES BY SAMARIUM DIIODIDE [J].

KENDE, AS ;

MENDOZA, JS .

TETRAHEDRON LETTERS, 1991, 32 (14) :1699-1702

[6] Organic derivatives of sulphur, selenium, and tellurium - Part I [J].

Lewis, DT .

JOURNAL OF THE CHEMICAL SOCIETY, 1940, :831-832

[7]

Sekiguchi M., 1991, HETEROAT CHEM, V2, P427, DOI [10.1002/hc.520020310, DOI 10.1002/HC.520020310]

[8]

WALBORSKY, 1992, J ORG CHEM, V57, P370

[9]

WANG JX, 1990, J CHEM RES-S, P230

[10] SOME DEOXYGENATION AND REDUCTION REACTIONS WITH SAMARIUM DIIODIDE [J].

ZHANG, YM ;

LIN, RH .

SYNTHETIC COMMUNICATIONS, 1987, 17 (03) :329-332

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