SYNTHESIS AND CHARACTERIZATION OF 5-COORDINATE [PTCL(L)(N-N)(OLEFIN)]+ COMPLEXES - MOLECULAR-STRUCTURE OF [PTCL(PYRIDINE)(2,9-DIMETHYL-1,10-PHENANTHROLINE)(ETHYLENE)]-(CF3SO3)

被引：30

作者：

ALBANO, VG

CASTELLARI, C

MONARI, M

DEFELICE, V

PANUNZI, A

RUFFO, F

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,VIA F SELMI 2,I-40126 BOLOGNA,ITALY

[2] UNIV MOLISE,FAC AGRARIA,I-86100 CAMPOBASSO,ITALY

[3] NAPLES UNIV,DIPARTIMENTO CHIM,I-80134 NAPLES,ITALY

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 11期

关键词：

D O I：

10.1021/om00059a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic five-coordinate platinum(II) complexes of general formula [PtCl(L)(N-N)(olefin)]+ have been synthesized. Relevant chemical and spectral properties of the new complexes are discussed in comparison with related five-coordinate species. The X-ray crystal structure of the title complex has been determined. This crystallizes in the orthorhombic system, space group Pbca with a = 12.808 (5) angstrom, b = 18.744 (4) angstrom, c = 19.445 (3) angstrom, and Z = 8. Refinement converged at R = 0.025 (R(w) = 0.027). The geometry of the five-coordinated platinum complex is bipyramidal, with the chloride and pyridine ligands in the apical positions and the olefin double bond in the equatorial plane.

引用

页码：3665 / 3669

页数：5

共 13 条

[1] SYNTHESIS AND CHARACTERIZATION OF 5-COORDINATE PLATINUM(II) COMPLEXES [PT(2,9-DIMETHYL-1,10-PHENANTHROLINE) (SNRNX3-N)X(OLEFIN)] (X = CL OR BR - R = PH OR ME) - MOLECULAR-STRUCTURE OF [PT(2,9-DIMETHYL-1,10-PHENANTHROLINE)(SNPH2CL)CL(ETHYLENE)]
ALBANO, VG
CASTELLARI, C
DEFELICE, V
PANUNZI, A
RUFFO, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 425 (1-2) : 177 - 188
[2] PREPARATION OF A 5-CO-ORDINATE PLATINUM-PI-ETHYLENE COMPLEX - (BIACETYL BISMETHYLPHENYLHYDRAZONE)DICHLORO-PI-ETHYLENEPLATINUM(II)
CATTALIN.L
GASPARRI.F
MARESCA, L
NATILE, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (11) : 369 - 370
[3] 5-COORDINATE OLEFIN COMPLEXES OF PLATINUM(II) CONTAINING SIGMA-BONDED CARBON LIGANDS - COORDINATION ENVIRONMENT AND STABILITY
CUCCIOLITO, ME
DEFELICE, V
PANUNZI, A
VITAGLIANO, A
[J]. ORGANOMETALLICS, 1989, 8 (05) : 1180 - 1187
[4] 4-VERSUS 5-CO-ORDINATION IN PALLADIUM(II) AND PLATINUM(II) COMPLEXES CONTAINING 2,9-DIMETHYL-1,10-PHENANTHROLINE (DMPHEN) - CRYSTAL-STRUCTURES OF [PTCL2(DMPHEN)] AND [PT(ETA-2-C2H4)CL2(DMPHEN)]
FANIZZI, FP
INTINI, FP
MARESCA, L
NATILE, G
LANFRANCHI, M
TIRIPICCHIO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (04): : 1007 - 1015
[5] PROTOPHANES AND POLYAROMATICS .22. NUCLEOPHILIC ALKYLATION AND ARYLATION OF 2,2'-BIPYRDYL
KAUFFMANN, T
KONIG, J
WOLTERMANN, A
[J]. CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (12): : 3864 - 3868
[6] 5-COORDINATE ETHYLENE COMPLEXES OF PLATINUM(II) CONTAINING DIFFERENT TYPES OF N-DONOR BIDENTATE LIGANDS
MARESCA, L
NATILE, G
CATTALINI, L
[J]. INORGANICA CHIMICA ACTA, 1975, 14 (01) : 79 - 82
[7] DECOMPOSITION OF [PT(C2H4)CL2(BIPYRIDYL) TO [PTCL2(BIPYRIDYL)] AND ETHYLENE IN DIFFERENT SOLVENTS
NATILE, G
MARESCA, L
CATTALINI, L
BELLUCO, U
UGUAGLIATI, P
CROATTO, U
[J]. INORGANICA CHIMICA ACTA, 1976, 20 (01) : 49 - 52
[8] NEW CATIONIC 5-COORDINATE MONOOLEFIN HYDROCARBYL COMPLEXES OF PLATINUM(II)
SANCHEZ, A
CASTELLARI, C
PANUNZI, A
VITAGLIANO, A
DEFELICE, V
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 388 (1-2) : 243 - 252
[9] NUCLEOPHILIC-ATTACK ON OLEFINS COORDINATED TO PLATINUM .4. FORMATION OF NEUTRAL AND CATIONIC SIGMA-ADDUCTS AND OF RING COMPOUNDS - STUDIES OF STABILITY
SARHAN, JKK
GREEN, M
ALNAJJAR, IM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (05): : 771 - 777
[10] SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

← 1 2 →