ANALYSIS OF ELECTROGENERATED FILMS BY ELLIPSOMETRY AND INFRARED SPECTROMETRY

被引：34

作者：

HAMNETT, A ^{[1
]}

CHRISTENSEN, PA ^{[1
]}

HIGGINS, SJ ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

来源：

ANALYST | 1994年 / 119卷 / 05期

关键词：

IN SITU SPECTROELECTROCHEMISTRY; CARBON DIOXIDE REDUCTION; POLY(PYRROLE); MODIFIED ELECTRODES; PRUSSIAN BLUE FILMS;

D O I：

10.1039/an9941900735

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The results of combined in situ Fourier transform infrared spectrometric and ellipsometric investigations of three types of film are reviewed, and the complementary nature of these two powerful techniques is explored. The films were chosen to represent three possible levels of redox centre interaction, varying from the essentially independent in poly(4-vinyl-4'methyl-2,2'-bipyridylrheniumtricarbonyl chloride) through optically coupled systems such as Prussian Blue to the strongly correlated systems exemplified by poly(pyrrole), and in each instance, the detailed behaviour of the film during growth and cycling can be derived.

引用

页码：735 / 747

页数：13

共 34 条

[1] CARBONYL HALIDES OF MANGANESE AND SOME RELATED COMPOUNDS [J].