LASER RAMAN AND INFRA-RED SPECTRA OF SOME THIOUREA AND SELENOUREA COMPLEXES OF PLATINUM (2) AND PALLADIUM (2)

被引：36

作者：

HENDRA, PJ

JOVIC, Z

机构：

[1] Department of Chemistry, The University, Southampton

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 11期

关键词：

D O I：

10.1016/0584-8539(68)80226-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The preparation, infra-red and laser Raman spectra of some novel selenourea complexes of platinum and palladium are reported. The data are compared with those from the analogous thiourea complexes. Assignments of spectral features to fundamental modes are attempted. The spectra are in agreement with those expected from non-distorted square planar derivatives. The frequencies of the Se-metal stretching modes are significantly higher than those observed for dimethylselenide complexes. The reverse is true when comparing thiourea and dimethylsulphide containing compounds. © 1968.

引用

页码：1713 / &

共 17 条

[1]

ADAMS DM, 1967, J CHEM SOC, pA884

[2] VIBRATIONAL SPECTRA OF CO-ORDINATION COMPOUNDS OF FORMULA TRANS- MX2Y2 .3. LOW-FREQUENCY VIBRATIONS OF GROUP 8 COMPLEXES WHERE X = CL BR AND I AND Y = ME2S ME2SE AND ME2TE [J].

ALLKINS, JR ;

HENDRA, PJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (08) :1325-&

[3] INFRARED SPECTRA (400-135 CM-1) OF SOME THIOUREA CO-ORDINATION COMPLEXES [J].

FLINT, CD ;

GOODGAME, M .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (06) :744-&

[4] SOME TRANSITION METAL COMPLEXES WITH SELENOCYANATE ION [J].

FORSTER, D ;

GOODGAME, DM .

INORGANIC CHEMISTRY, 1965, 4 (12) :1712-&

[5] INFRARED SPECTRA (400-200 CM.-1) OF SOME THIOCYANATE AND ISOTHIOCYANATE COMPLEXES [J].

FORSTER, D ;

GOODGAME, DM .

INORGANIC CHEMISTRY, 1965, 4 (05) :715-+

[6] CRYSTAL AND MOLECULAR STRUCTURES OF CIS SQUARE-PLANAR COMPLEXES OF TELLURIUM DICHLORIDE AND DIBROMIDE WITH THIOUREA [J].

FOSS, O ;

JOHNSEN, K ;

MAARTMAN.KM ;

MAROY, K .

ACTA CHEMICA SCANDINAVICA, 1966, 20 (01) :113-&

[7] RAMAN SPECTRA OF A SERIES OF SQUARE PLANAR ANIONS [J].

HENDRA, PJ .

NATURE, 1966, 212 (5058) :179-&

[8] RAMAN SPECTRA OF COMPLEX ANIONS OF FORMULA MX4N- WHERE M IS AU3 PT2 OR PD2 AND X IS A HALOGEN ATOM [J].

HENDRA, PJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (08) :1298-&

[9]

KURNAKOW N, 1894, J PRAKT CHEM, V50, P485

[10] INFRARED SPECTRA OF METAL CHELATE COMPOUNDS .9. A NORMAL COORDINATE ANALYSIS OF DITHIOCARBAMATO COMPLEXES [J].

NAKAMOTO, K ;

CONDRATE, RA ;

FUJITA, J ;

MORIMOTO, Y .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (02) :423-&

← 1 2 →