UNEXPECTED REVERSAL OF REGIOSELECTIVITY IN THE PALLADIUM-CATALYZED ADDITION OF THE TIN GERMANIUM BOND TO ALLENES

被引：31

作者：

MITCHELL, TN

SCHNEIDER, U

FROHLING, B

机构：

[1] Fachbereich Chemie, Universität Dortmund, 4600 Dortmund 50

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 384卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)87134-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Whereas the addition of tributyl(trimethylgermyl)stannane to 1-alkynes in the presence of tetrakis(triphenylphosphine)palladium proceeds regiospecifically, the direction of its addition to allenes is dependent on the structure of the allene. © 1990.

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页码：C53 / C56

页数：4

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