POLY(BENZOTRIAZOLYL)BORATES .1. LIGAND SYNTHESIS AND CHARACTERIZATION

被引：40

作者：

LALOR, FJ

MILLER, SM

GARVEY, N

机构：

[1] Department of Chemistry, University College, Cork

来源：

POLYHEDRON | 1990年 / 9卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)84248-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of the new potassium poly(azolyl)borate salts KH2B(C6H4N3)2, KHB(C6H4N3)3 and KB(C6H4N3)4 (C6H4N3 = benzotriazolyl) and their thallium(I) derivatives is described. 13C NMR spectroscopy identifies the anions as the N(1)-regioisomers and suggests a similar structure for the tetrakis(indazolyl)borate anion [B(C7H5N2)4]-. The unexpected regioisomerism of the anions-which differs from that of related species-is attributed to the importance of electronic effects. © 1990.

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页码：63 / 68

页数：6

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