HIGHLY EFFICIENT NITROALDOL REACTION PROMOTED BY TRIALKYLSILYL CHLORIDES

被引：23

作者：

FERNANDEZ, R

GASCH, C

GOMEZSANCHEZ, A

VILCHEZ, JE

机构：

[1] UNIV SEVILLA, DEPT QUIM ORGAN PROFESOR GARCIA GONZALEZ, APARTADO CORREOS 553, E-41071 SEVILLE, SPAIN

[2] CSIC, INST GRASA & DERIVADOS, E-41071 SEVILLE, SPAIN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)79729-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Beta-Nitroalcohols can be readily obtained in high yields by the one-pot reaction of aldehydes with nitrocompounds in the presence of Et3N, Bu4NF.3H2O and (t)BuMe2SiCl. Model experiments indicated that trialkylsilyl nitronic esters are not reaction intermediates.

引用

页码：3225 / 3228

页数：4

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