HIGHLY EFFICIENT NITROALDOL REACTION PROMOTED BY TRIALKYLSILYL CHLORIDES

被引:23
作者
FERNANDEZ, R
GASCH, C
GOMEZSANCHEZ, A
VILCHEZ, JE
机构
[1] UNIV SEVILLA, DEPT QUIM ORGAN PROFESOR GARCIA GONZALEZ, APARTADO CORREOS 553, E-41071 SEVILLE, SPAIN
[2] CSIC, INST GRASA & DERIVADOS, E-41071 SEVILLE, SPAIN
关键词
D O I
10.1016/S0040-4039(00)79729-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Beta-Nitroalcohols can be readily obtained in high yields by the one-pot reaction of aldehydes with nitrocompounds in the presence of Et3N, Bu4NF.3H2O and (t)BuMe2SiCl. Model experiments indicated that trialkylsilyl nitronic esters are not reaction intermediates.
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页码:3225 / 3228
页数:4
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