AEROBIC EPOXIDATION OF HINDERED OLEFINS AND ENOL ETHERS CATALYZED BY A POLYMERIZABLE BETA-KETOESTERATE COMPLEX OF IRON(III)

被引：15

作者：

LOPEZ, L

MASTRORILLI, P

MELE, G

NOBILE, CF

机构：

[1] POLITECN BARI,IST CHIM,MISO,CTR CNR,I-70126 BARI,ITALY

[2] UNIV BARI,DIPARTMENTO CHIM,MISO,CTR CNR,I-70126 BARI,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)73259-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Peculiar hindered olefins and derivatives have been epoxidized, under Mukaiyama's conditions, using iron(III) catalytic centres. The experimental results allow to rule out the involvement of singlet oxygen and free peroxyacids as active species.

引用

页码：3633 / 3636

页数：4

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