IDENTIFICATION OF 11,15-OCTADECADIENOIC ACID FROM BEEF AND MUTTON TALLOW

被引：18

作者：

HOFFMANN, G

MEIJBOOM, PW

机构：

[1] Unilever Research Laboratory, Vlaardingen

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1969年 / 46卷 / 11期

关键词：

D O I：

10.1007/BF02544981

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

By means of gas liquid chromatography and thin layer chromatography on Silica gel G/AgNO 3 we isolated some isolinoleic acids from beef and mutton tallow, which by their chromatographical behavior, IR analysis and by double bond determination by ozonolysis are mainly stereo-isomeric 11,15-octadecadienoic acids and in a smaller amount stereo-isomers of 10,15-octadecadienoic acids. 4-Cis- and 4-trans-heptenals, 2-trans,6-cis- and 2-trans,6-trans-nonadienals have been isolated from the DNPH mixture obtained from the volatile decomposition products of an oxidized synthetic mixture of stereo-isomeric 11,15-octadecadienoic acids. © 1969 AOCS Press.

引用

收藏

页码：620 / &

相关论文

共 10 条

[1] RAPID DETERMINATION OF OLEFIN POSITION IN ORGANIC COMPOUNDS IN MICROGRAM RANGE BY OZONOLYSIS AND GAS CHROMATOGRAPHY [J].

BEROZA, M ;

BIERL, BA .

ANALYTICAL CHEMISTRY, 1967, 39 (10) :1131-&

[2] ISOLATION OF VOLATILE CONSTITUENTS FROM FATS AND OILS BY VACUUM DEGASSING [J].

DEBRUYN, J ;

SCHOGT, JCM .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1961, 38 (01) :40-44

[3] IDENTIFICATION OF SOME ISO-LINOLEIC ACIDS OCCURRING IN BUTTERFAT [J].

DEJONG, K ;

VANDERWE.H .

NATURE, 1964, 202 (493) :553-&

[4] QUANTITATIVE SEPARATIONS OF HIGHER FATTY ACID METHYL ESTERS BY ADSORPTION CHROMATOGRAPHY ON SILICA IMPREGNATED WITH WILVER NITRATE [J].

DEVRIES, B .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1963, 40 (05) :184-&

[5]

HAVERKAMP BP, 1964, NATURE, V202, P552

[6]

HAVERKAMP BP, 1959, RECL TRAV CHIM PAY B, V78, P275

[7] ISOLATION OF 2 ISOMERIC 2,6-NONADIENALS AND 2 ISOMERIC 4-HEPTENALS FROM BEEF AND MUTTON TALLOW [J].

HOFFMANN, G ;

MEIJBOOM, PW .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1968, 45 (06) :468-&

[8] SEPARATION AND IDENTIFICATION OF 2,4-DINITROPHENYLHYDRAZONES OF UNSATURATED ALDEHYDES AND METHYLKETONES BY THIN-LAYER CHROMATOGRAPHY [J].

MEIJBOOM, PW .

FETTE SEIFEN ANSTRICHMITTEL VERBUNDEN MIT DER ZEITSCHRIFT DIE ERNAHRUNGSINDUSTRIE, 1968, 70 (07) :477-&

[9] SYNTHESIS OF 11CIS 15CIS- AND 10CIS 15CIS-OCTADECADIENOIC ACID PROBABLE PRECURSORS OF 4CIS-HEPTENAL IN AUTOXIDIZED BUTTERFAT [J].

PABON, HJJ ;

VANDORP, DA .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1969, 46 (05) :269-&

[10] OCTADECADIENOIC ACIDS OF LAMB CAUL FAT [J].

WEENINK, RO .

NATURE, 1956, 178 (4534) :646-647