POLYHEDRAL B6C2H8, B7C2H9, AND B8C2H10 CARBORANES AND THEIR C-MONOMETHYL AND C-MONOPHENYL DERIVATIVES

被引：56

作者：

GARRETT, PM

SMART, JC

DITTA, GS

HAWTHORN.MF

机构：

[1] Department of Chemistry, University of California, Riverside

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 09期

关键词：

D O I：

10.1021/ic50079a021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pyrolysis of 1,3-B7C2H12 at 215° in the absence of diborane yields the B6C2H3, B7C2H9, and 1,6-B8C2H10 carboranes, while in the presence of diborane the yield of 1,6-B8C2H10 is considerably enhanced. Isomerization of 1,6-B8C2H10 to the 1,10- B8C2H10 isomer occurs at 300°. Pyrolysis of l,3-NaB7C2H12 at 200° yields 1,7-B7C2H9. The C-monomethyl and C-monophenyl derivatives of these carboranes are also described. © 1969, American Chemical Society. All rights reserved.

引用

页码：1907 / &

共 9 条

[1]

Brown H. C., 1962, HYDROBORATION

[2]

DUNKS GB, 1968, INORG CHEM, V7, P1030

[3] OXIDATION OF (3)-1,7-DICARBA-NIDO-DODECAHYDROUNDECABORATE(-1) ION . A NEW PREPARATION OF 1,3-DICARBA-NIDO-NONABORANE(13) [J].