INHOMOGENEOUS AND HOMOGENEOUS BROADENINGS OF OPTICAL AND ODMR TRANSITIONS OF TRIPLET-STATES IN SOLIDS

被引:25
作者
LEMAISTRE, JP
ZEWAIL, AH
机构
[1] Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena
关键词
D O I
10.1016/0009-2614(79)87204-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple mechanism for the broadening of optical and ODMR transitions of guest molecules in both lattices is provided. According to this mechanism the broadening results from the random spin-orbital interactions caused by electronic energy fluctuations (inhomogeneous) in the singlet and triplet states. Comparison of the theoretical findings of the model with experiments is made and new predictions are given. © 1979.
引用
收藏
页码:296 / 301
页数:6
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