CALORIMETRIC INVESTIGATION OF BROMINE ADDITION-REACTIONS FOR STRUCTURAL DETERMINATION AND QUANTITATIVE-ANALYSIS

被引：2

作者：

MARIKKORDA, P

ECKHART, E

机构：

[1] Lehrstuhl für Allgemeine und Analytische Chemie, Technische UniversitÄt Budapest, Budapest

来源：

JOURNAL OF THERMAL ANALYSIS | 1979年 / 17卷 / 01期

关键词：

D O I：

10.1007/BF02156611

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Organic substances containing double bonds, e.g. allyl alcohol, and different medicaments (quinine, vasalgin), were determined with bromine water by direct injection enthalpimetry. Measurement of the reaction heat or the rate of evolution of heat permits simple and rapid distinction of cis and trans isomers: fumaric and maleic acid, or oleic and elaidinic acid. © 1979 Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest.

引用

页码：171 / 176

页数：6

共 9 条

[1]

DOERING K, 1972, Z ANAL CHEM, V258, P177

[2] DIRECT DEMONSTRATION OF IONIC INTERMEDIATES IN ELECTROPHILIC BROMOADDITION TO OLEFINS [J].