HOMOLYTIC SUBSTITUTION ON SELENIUM - FORMATION OF SELENIUM-CONTAINING HETEROCYCLES BY DIRECT CARBON-SELENIUM BOND FORMATION

被引：38

作者：

SCHIESSER, CH

SUTEJ, K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thiohydroxamic esters derived from 5-(benzylseleno)pentanoic acid, 6-(benzylseleno)hexanoic acid and 7-(benzylseleno)heptanoic acid decompose smoothly upon irradiation, with the loss of carbon dioxide, to give tetrahydroselenophene, selenane and selenopane in good yield.

引用

收藏

页码：57 / 59

页数：3

相关论文

共 27 条

[1] FLUXIONAL CHARACTERISTICS OF PALLADIUM(II) HALIDE-COMPLEXES OF CYCLIC SELENOETHERS - A DYNAMIC NUCLEAR-MAGNETIC-RESONANCE STUDY [J].

ABEL, EW ;

MACKENZIE, TE ;

ORRELL, KG ;

SIK, V .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (01) :205-211

[2]

[Anonymous], 1986, AB INITIO MOL ORBITA

[3] TRIS(TRIMETHYLSILYL)SILANE AS A RADICAL-BASED REDUCING AGENT IN SYNTHESIS [J].

BALLESTRI, M ;

CHATGILIALOGLU, C ;

CLARK, KB ;

GRILLER, D ;

GIESE, B ;

KOPPING, B .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) :678-683

[4] THE INVENTION OF NEW RADICAL CHAIN REACTIONS .8. RADICAL CHEMISTRY OF THIOHYDROXAMIC ESTERS - A NEW METHOD FOR THE GENERATION OF CARBON RADICALS FROM CARBOXYLIC-ACIDS [J].

BARTON, DHR ;

CRICH, D ;

MOTHERWELL, WB .

TETRAHEDRON, 1985, 41 (19) :3901-3924

[5] STEREOCHEMISTRY OF INTRAMOLECULAR HOMOLYTIC SUBSTITUTION AT THE SULFUR ATOM OF A CHIRAL SULFOXIDE [J].

BECKWITH, ALJ ;

BOATE, DR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (03) :189-190

[6] FORMATION OF FUSED TRICYCLIC AZETIDINONES AND PYRROLIDINONES BY INTRAMOLECULAR SH2 PROCESSES [J].

BECKWITH, ALJ ;

BOATE, DR .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (18) :4339-4348

[7] RELATIVE REACTIVITIES OF VARIOUS SULFIDES, SELENIDES AND HALIDES TOWARDS SH2 ATTACK BY TRIBUTYLTIN RADICALS [J].

BECKWITH, ALJ ;

PIGOU, PE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (01) :77-87

[8] FORMATION OF FUSED BI-CYCLIC AND TRI-CYCLIC BETA-LACTAMS BY RADICAL RING-CLOSURE [J].

BECKWITH, ALJ ;

BOATE, DR .

TETRAHEDRON LETTERS, 1985, 26 (14) :1761-1764

[9] INTRAMOLECULAR FREE-RADICAL SUBSTITUTION AT SULFUR ATOM IN SULFIDES [J].

BENATI, L ;

MONTEVECCHI, PC ;

TUNDO, A ;

ZANARDI, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1974, (11) :1272-1276

[10] HEXENYL RADICAL CYCLIZATION VIA PHENYL SELENIDE TRANSFER [J].

BYERS, JH ;

GLEASON, TG ;

KNIGHT, KS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (06) :354-356