A MECHANISM OF LITHIUM STORAGE IN DISORDERED CARBONS

被引:702
作者
SATO, K [1 ]
NOGUCHI, M [1 ]
DEMACHI, A [1 ]
OKI, N [1 ]
ENDO, M [1 ]
机构
[1] SHINSHU UNIV,FAC ENGN,NAGANO 380,JAPAN
关键词
D O I
10.1126/science.264.5158.556
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
High-resolution electron microscopy and lithium-7 nuclear magnetic resonance measurements were carried out for a disordered carbon material, prepared by heat treatment of polyphenylene, in which lithium was stored electrochemically. The nuclear magnetic resonance spectrum suggests the existence of Li-2 covalent molecules in the carbon material. This extra covalent site of lithium storage promises extraordinarily high energy density for secondary batteries.
引用
收藏
页码:556 / 558
页数:3
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