REDUCTION OF CARBON-DIOXIDE BY NICKEL MACROCYCLIC CATALYSTS ADSORBED ON A MERCURY-ELECTRODE OR A COPPER ROTATING-DISC ELECTRODE

被引：36

作者：

SMITH, CI ^{[1
]}

CRAYSTON, JA ^{[1
]}

HAY, RW ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 21期

关键词：

D O I：

10.1039/dt9930003267

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for evaluating the efficiency of nickel macrocyclic electrocatalysts for reduction of CO2 to CO using a rotating copper disc electrode has led to the discovery of a new highly active complex, [NiL2]2+ [L2 = 3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane (diazacyclam)].

引用

页码：3267 / 3269

页数：3

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