A NEW PHASE OF BIS[2-(DIPHENYLPHOSPHINO-KAPPA-P-PHENYLAZANIDO-KAPPA-N](ETHANOLATO)(OXO)-RHENIUM(V)

被引：9

作者：

BANDOLI, G ^{[1
]}

DOLMELLA, A ^{[1
]}

TISATO, F ^{[1
]}

REFOSCO, F ^{[1
]}

机构：

[1] CNR,IST CHIM & TECNOL INORGAN & MAT AVANZATI,I-35020 PADUA,ITALY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193010029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Re(C18H15NP)2(C2H5O)O], was synthesized by the oxidation-substitution reaction of [Re(III)(PNH)2(PNH2)]Cl, where PNH2 is 2-(diphenylphosphino)phenylamine, with NEt3 in EtOH. The X-ray diffraction study of this new triclinic phase, designated beta, confirms the molecular structural details for the monoclinic a isomer, which crystallized in space group P2(1)/c with a = 12.056 (3), b = 26.303 (6), c = 11.005 (3) angstrom, beta = 102.32 (2)-degrees [Refosco, Tisato, Bandoli, Bolzati, Dolmella, Moresco & Nicolini (1993). J. Chem. Soc. Dalton Trans. pp. 605-618].

引用

页码：530 / 532

页数：3

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[5] COORDINATION OF (O-AMINOPHENYL)DIPHENYLPHOSPHINE IN COMPLEXES CONTAINING THE [MV=O]3+ (M=TC OR RE) CORE [J].

REFOSCO, F ;

TISATO, F ;

BANDOLI, G ;

BOLZATI, C ;

DOLMELLA, A ;

MORESCO, A ;

NICOLINI, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04) :605-618

[6]

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