MONONUCLEAR AND BINUCLEAR RHODIUM COMPLEXES OF A CHIRAL 1,1-DIPHOSPHINE - SYNTHESES AND CRYSTAL-STRUCTURES

被引：23

作者：

MARINETTI, A

LEMENN, C

RICARD, L

机构：

[1] Laboratoire “Hétéroéléments et Coordination”, URA CNRS 1499, DCPH, Ecole Polytechnique

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 11期

关键词：

D O I：

10.1021/om00011a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homochiral diphosphine 3, bearing PPh(2) and menthylphosphetane moieties, has been prepared from the phosphetane oxide 1 through a stereoselective phosphorylation reaction. Monometallic and bimetallic ''A-frame'' rhodium complexes of 3 have been synthesized and characterized by X-ray diffraction.

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页码：4983 / 4985

页数：3

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