SYNTHESIS, VIBRATIONAL ANALYSIS, AND SINGLE-CRYSTAL STRUCTURE OF TETRAMETHYLAMMONIUMCYANATE [N(CH3)(4)]OCN

被引：9

作者：

ALBERT, B

JANSEN, M

机构：

[1] Institut Für Anorganische Chemie, Universität Bonn, D‐53121

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 03期

关键词：

TETRAMETHYLAMMONIUMCYANATE; SYNTHESIS; CRYSTAL STRUCTURE; VIBRATIONAL ANALYSIS;

D O I：

10.1002/zaac.19956210322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By ionic exchange pure tetramethylammoniumcyanate [N(Ch(3))]4OCN was synthesized for the first time. Single crystals were investigated on a 4-circle-diffractometer. Structure solution and refinement was done in Pmn2(1). The structure may be derived from the CsCl-type with linear, non-symmetric cyanate-anions and tetrahedral, slightly distorted tetramethylammonium-cations Vibrational spectra confirm the distortion of the cation which can be caused by weak O...H(C)-interactions.

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页码：464 / 468

页数：5

相关论文

共 23 条

[1] WHY DOES TETRAMETHYLAMMONIUM OXALATE EXHIBIT SUBLIMATION [J].

ALBERT, B ;

JANSEN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (11) :965-966

[2]

ALBERT B, THESIS U BONN

[3]

Bassiere M, 1938, CR HEBD ACAD SCI, V206, P1309

[4] VIBRATIONAL-SPECTRUM OF NORMAL AND PERDEUTERATED TETRAMETHYLAMMONIUM ION [J].

BERG, RW .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1978, 34 (06) :655-659

[5] The crystal structure of calcium cyanamide [J].

Bredig, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :1730-1731

[6] CRYSTAL STRUCTURE OF SILVER CYANATE [J].

BRITTON, D ;

DUNITZ, JD .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :424-&

[7] NEW SYNTHESIS, CRYSTAL-STRUCTURE, AND VIBRATIONAL-SPECTRA OF TETRAMETHYLAMMONIUM AZIDE AND REACTIONS OF THE FLUORIDE ANION WITH HN3 AND OF THE AZIDE ANION WITH HF [J].

CHRISTE, KO ;

WILSON, WW ;

BAU, R ;

BUNTE, SW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (09) :3411-3414

[8] CARBONIUM ION SALTS .9. HYDROGEN DIHALIDES [J].

HARMON, KM ;

ALDERMAN, SD ;

BENKER, KE ;

DIESTLER, DJ ;

GEBAUER, PA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (08) :1700-+

[9] HYDROGEN-BONDING .4. CORRELATION OF INFRARED SPECTRAL PROPERTIES WITH C-H TRIPLE BOND X HYDROGEN-BONDING AND CRYSTAL HABIT IN TETRAMETHYLAMMONIUM ION SALTS [J].

HARMON, KM ;

GENNICK, I ;

MADEIRA, SL .

JOURNAL OF PHYSICAL CHEMISTRY, 1974, 78 (25) :2585-2591

[10] The crystal structures of sodium and potassium trinitrides and potassium cyanate and the nature of the trinitride group [J].

Hendricks, SB ;

Pauling, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1925, 47 :2904-2920