STUDIES ON COMPLEXES .14. ACCEPTOR PROPERTIES AND STRUCTURE OF 1,4-BISDIAZOCYCLOHEXANETETRAONE C6N4O4

被引：4

作者：

ANSELL, GB

HAMMOND, PR

HERING, SV

CORRADIN.P

机构：

[1] Michelson Laboratories, Naval Weapons Centre, China Lake

来源：

TETRAHEDRON | 1969年 / 25卷 / 12期

关键词：

D O I：

10.1016/S0040-4020(01)82800-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chemical properties of the title compound are described briefly. Coloured solutions with aromatic hydrocarbons, dimethylaniline and polymethoxybenzenes are attributed to 1:1 interactions and equilibrium constants and enthalpies are reported. One, deep-red tetramethoxybenzene complex is isolated. Polarographic reduction in aprotic solvents is irreversible and is compared with the potentials for other acceptors. The compound is a weaker acceptor than trinitrobenzene. An X-ray crystallographic study shows that the molecule is most accurately represented as a bis(diazonium oxide) structure. © 1969.

引用

页码：2549 / &

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