CONDENSATION OF CARBANIONS WITH 1,3,5-TRINITROBENZENE - A NEW TYPE OF BICYCLIC ANION

被引：22

作者：

FOREMAN, MI

FOSTER, R

STRAUSS, MJ

机构：

[1] Chemistry Department, University of Dundee

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 16期

关键词：

D O I：

10.1039/j39690002112

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3,5-Trinitrobenzene can react with certain ketonic compounds in the presence of a base to form a new type of bicyclic anion. This reaction has been observed with pentane-2,4-dione, with dibenzyl ketone, and with ethyl acetoacetate. A previously unidentified product from the reaction of 1,3,5-trinitrobenzene with acetone in the presence of diethylamine is now identified as such a bicyclic product.

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页码：2112 / &

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