The electronic structure of benzene

被引：54

作者：

Lindholm, E. ^{[1
]}

Jonsson, B. -Oe. ^{[1
]}

机构：

[1] Royal Inst Technol, Dept Phys, S-10044 Stockholm 70, Sweden

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 10期

关键词：

D O I：

10.1016/0009-2614(67)85090-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The orbital energies of benzene from photoelectron spectroscopy measurements have been discussed by use of electron impact energy loss measurements and mass-spectrometric measurements. Between the pi-orbitals at 9.3 eV and 12.1 eV there is a sigma-orbital at 11.4 eV. Also the remaining molecular orbitals have been identified.

引用

页码：501 / 503

页数：3

共 14 条

[1] MOLECULAR PHOTOELECTRON SPECTROSCOPY .2. SUMMARY OF IONIZATION POTENTIALS [J].

ALJOBOURY, MI ;

TURNER, DW .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (NOV) :4434-&

[2] ELECTRONIC EXCITED STATES OF BENZENE AND ETHYLENE [J].

CLARK, PA ;

RAGLE, JL .

JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (11) :4235-&

[3] IONIZATION POTENTIALS OF BENZENE, HEXADEUTEROBENZENE, AND PYRIDINE FROM THEIR OBSERVED RYDBERG SERIES IN REGION 600-2000 A [J].

ELSAYED, MF ;

KASHA, M .

JOURNAL OF CHEMICAL PHYSICS, 1961, 34 (01) :334-&

[4]

HERZBERG G, 1966, MOL SPECTRA MOL STRU, V3, P341

[5] AN EXTENDED HUCKEL THEORY .I. HYDROCARBONS [J].

HOFFMANN, R .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (06) :1397-&

[6]

LASSETTRE EN, COMMUNICATION

[7]

LINDHOLM E, 1966, ADV CHEM SER, V58, P1

[8] HIGHER IONIZATION POTENTIALS OF CHLOROBENZENE [J].

MAY, DP ;

TURNER, DW .

CHEMICAL COMMUNICATIONS, 1966, (07) :199-&

[9] MOLECULAR ORBITALS FOR ORGANIC SYSTEMS PARAMETRIZED FROM SCF MODEL CALCULATIONS [J].

NEWTON, MD ;

BOER, FP ;

LIPSCOMB, WN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (11) :2367-+

[10] The far ultraviolet absorption spectra and ionization potentials of C6H6 and C6D6 [J].

Price, WC ;

Wood, RW .

JOURNAL OF CHEMICAL PHYSICS, 1935, 3 (08) :439-444

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