PRODUCTION AND MAGIC NUMBERS OF LARGE HYDRATED ANION CLUSTERS X-(H2O)N=0-59 (X = OH, O, O2, AND O3) UNDER THERMAL CONDITIONS

被引：86

作者：

YANG, X ^{[1
]}

CASTLEMAN, AW ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 23期

关键词：

D O I：

10.1021/j100386a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Large X-(H2O)n=0-59 (X = OH, O, O2, and O3) negative cluster ions were, for the first time, produced and studied in a flow tube reactor under well-defined temperatures and pressures. Magic numbers at n = 11, 14, 17, and 20 for OH-(H2O)n and O-(H2O)n are observed which are consistent with expected structures involving stable closed six-member and five-member rings. Comparison is made of the observations of magic numbers of the hydrated OH- and H3O+ clusters, and some interesting analogies between the two kinds of clusters are indicated. © 1990 American Chemical Society.

引用

页码：8500 / 8502

页数：3

共 38 条

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