CRYSTAL AND MOLECULAR-STRUCTURE OF [CO(ETA(5)-C5H5)(CO)2]

被引：14

作者：

ANTIPIN, MY

STRUCHKOV, YT

CHERNEGA, AN

MEIDINE, MF

NIXON, JF

机构：

[1] UKRANIAN ACAD SCI,INST ORGAN CHEM,KIEV 253660,UKRAINE,USSR

[2] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 436卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)85028-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of [Co(eta-5-C5H5)(CO)2] has been determined by a single crystal X-ray diffraction study at -120-degrees-C. There are differences in the C-C bond lengths within the cyclopentadienyl ring that are in agreement with theoretical predictions.

引用

页码：79 / 82

页数：4

共 5 条

[1] STRUCTURAL-ANALYSIS OF (PENTAMETHYLCYCLOPENTADIENYL)COBALT(I) DICARBONYL - EVIDENCE FOR AN ELECTRONICALLY INDUCED DISTORTION OF THE CYCLOPENTADIENYL RING DUE TO ITS INTERACTION WITH A PLANAR CO(CO)2 FRAGMENT [J].