VIRIDIN .6. EVIDENCE FOR A STEROIDAL PATHWAY IN BIOGENESIS OF VIRIDIN FROM MEVALONIC ACID

被引:26
作者
GROVE, JF
机构
[1] University Chemical Laboratory, Cambridge
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 04期
关键词
D O I
10.1039/j39690000549
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[14C]Viridin, derived from [2-14C]mevalonate, has a labelling pattern consistent with its biogenesis by tail-to-tail condensation of two farnesyl residues. The carbon at position 4 is apparently derived from the methyl group of mevalonate. The absolute configuration (V) is deduced for viridin.
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页码:549 / &
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