FORMATION OF 9-OCTALIN (1,2,3,4,5,6,7,8-OCTAHYDRONAPHTHALENE) RADICAL CATIONS ON ADSORPTION OF ACYCLIC DIENES ONTO H-MORDENITE

被引：19

作者：

RHODES, CJ

STANDING, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 09期

关键词：

D O I：

10.1039/p29920001455

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Following the adsorption of (Z)- or (E)-piperylene (penta-1,3-diene), penta-1,4-diene or hexa-1,5-diene onto H-mordenite, EPR signals characteristic of 9-octalin radical cations 1/6 were recorded. Comparative studies of these dienes were made in solid freon matrices which indicate that a dominant mechanism involving Bronsted acid catalysis is required to explain the main molecular transformations, prior to radical cation formation.

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页码：1455 / 1460

页数：6

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