NEW RATE PRODUCT CORRELATIONS FOR GENERAL-BASE CATALYZED-REACTIONS IN ALCOHOL WATER MIXTURES

被引：20

作者：

BENTLEY, TW

JONES, RO

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 05期

关键词：

D O I：

10.1039/p29920000743

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selectivities (S) for solvolyses of p-nitrobenzoyl chloride (1), p-nitrobenzenesulfonyl chloride (2), p-nitrobenzyl chloride (3; Z = NO2) and p-methoxybenzyl chloride (3; Z = OMe) in alcohol-water mixtures are consistent with third-order terms in the rate law, including terms for nucleophilic attack and general-base catalysis by water and/or alcohol. The results document new rate-product correlations and new reactivity-selectivity relationships, which help to define 'normal' behaviour from which deviations can be identified for further investigations.

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页码：743 / 744

页数：2

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