FOURIER-TRANSFORM IR PRODUCT STUDY OF THE REACTION OF CFO RADICALS WITH O2 AT 298-K

被引：7

作者：

AHONKHAI, SI

NOLLE, A

BEHR, P

HEYDTMANN, H

机构：

[1] JW GOETHE UNIV FRANKFURT,INST PHYS & THEORET CHEM,MARIE CURIE STR 11,D-60439 FRANKFURT,GERMANY

[2] UNIV BENIN,DEPT CHEM,BENIN CITY,NIGERIA

[3] DEUTSCH FORSCHUNGSANSTALT LUFT & RAUMFAHRT,DFD,D-82230 OBERPFAFFENHOFEN,GERMANY

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1994年 / 80卷 / 1-3期

关键词：

D O I：

10.1016/1010-6030(94)85008-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experimental results are presented of a Fourier transform IR product study at 298 K of the reaction system CFO+O2 at oxygen pressures between 3 and 250 mbar. Pulsed photolysis of oxalyl fluoride (CFO)2 or formyl fluoride (CHFO) at 193 nm was used to produce CFO. As stable products we detected bis-fluoroformyl peroxide, carbonyl fluoride and carbon dioxide. The yields of the peroxide and of CF2O were measured as a function of [O2]/[precursor] and are discussed qualitatively.

引用

页码：389 / 392

页数：4

共 23 条

[1] THE REACTION OF FLUORINE-ATOMS WITH FORMYL FLUORIDE AND THE CFO SELF-REACTION AT 293-K [J].