ANOMALOUS PROPERTIES OF FLUORINE

被引：80

作者：

POLITZER, P

机构：

[1] Department of Chemistry, Louisiana State University New Orleans, New Orleans

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 23期

关键词：

D O I：

10.1021/ja01051a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Evidence is presented to show that the interaction of a fluorine atom with an external electron, as in the formation of an ionic or covalent bond, is accompanied by an anomalous destabilization energy of about 26 kcal/mole. It is suggested that this is the reason for the unusually low dissociation energy of the fluorine molecule. © 1969, American Chemical Society. All rights reserved.

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页码：6235 / &

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