ADSORPTION OF STRATOSPHERICALLY IMPORTANT MOLECULES ON THIN D2O ICE FILMS USING REFLECTION ABSORPTION INFRARED-SPECTROSCOPY

被引：104

作者：

HORN, AB

CHESTERS, MA

MCCOUSTRA, MRS

SODEAU, JR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1992年 / 88卷 / 07期

关键词：

D O I：

10.1039/ft9928801077

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of DCl, CCl4, CFCl3, CF2Cl2 and CF3Cl on thin D2O ice films at 110 K has been studied using reflection-absorption infrared spectroscopy (RAIRS). These compounds interact to varying degrees with the ice surface via the OD bonds dangling into the vacuum. DCl was found to dissociate ionically, evidenced by a strong band attributable to D3O+ and the absence of any absorption band for molecular DCl.

引用

页码：1077 / 1078

页数：2

共 18 条

[1] INFRARED-SPECTRUM OF WATER HYDROCHLORIC ACID COMPLEX IN SOLID NITROGEN
AULT, BS
PIMENTEL, GC
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (01) : 57 - 61
[2] INFRARED-SPECTROSCOPY OF MOLECULES ON METAL SINGLE-CRYSTAL SURFACES
CHESTERS, MA
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1986, 38 (1-4) : 123 - 140
[3] INFRARED-SPECTRA OF GAS-PHASE WATER MICROPARTICLES - CRYSTALLINE, AMORPHOUS, AND CLATHRATE HYDRATE CLUSTERS OF H2O, D2O, AND H2O/D2O
DEVLIN, JP
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (09) : 5850 - 5851
[4] HORN AB, IUNPUB
[5] KOEHLER BG, IN PRESS J GEOPHYS R
[6] HETEROGENEOUS REACTIONS OF CHLORINE NITRATE AND HYDROGEN-CHLORIDE ON TYPE-I POLAR STRATOSPHERIC CLOUDS
LEU, MT
MOORE, SB
KEYSER, LF
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) : 7763 - 7771
[7] FREE-JET INFRARED-ABSORPTION SPECTROSCOPY OF RARE GAS-(BF3)-B-11 COMPLEXES IN THE 7 MU-M REGION
MATSUMOTO, Y
OHSHIMA, Y
TAKAMI, M
KUCHITSU, K
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (12) : 7017 - 7021
[8] PRODUCTION OF CL2O2 FROM THE SELF-REACTION OF THE CIO RADICAL
MOLINA, LT
MOLINA, MJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (02) : 433 - 436
[9] HETEROGENEOUS REACTIONS ON NITRIC-ACID TRIHYDRATE
MOORE, SB
KEYSER, LF
LEU, MT
TURCO, RP
SMITH, RH
[J]. NATURE, 1990, 345 (6273) : 333 - 335
[10] NIXON ER, 1970, J CHEM PHYS, V52, P1521

← 1 2 →