SOLUBLE CATALYST PRECURSORS FOR DEHYDROGENATIVE POLYMERIZATION REACTION

被引：9

作者：

Chiang, Long Y. ^{[1
]}

Swirczewski, J. W. ^{[1
]}

Chianelli, R. R. ^{[1
]}

Stiefel, E. I. ^{[1
]}

机构：

[1] Exxon Res & Engn Co, Corp Res Labs, Annandale, NJ 08801 USA

来源：

CATALYSIS LETTERS | 1988年 / 1卷 / 05期

关键词：

D O I：

10.1007/BF00765901

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two soluble catalyst precursors, Re(abt)(3) and Re(abt)(2)(C6H4NS) can be used to generate rhenium sulfides insitu, which catalyze polyqninoline synthesis by dehydrogenative polymerization reactions. The reactive rhenium sulfides were found to have a chemical stoichiornetry close to ReS2.

引用

页码：177 / 182

页数：6

共 6 条

[1]

Chiang L.Y., 1986, P POLYM MAT SCI ENG, V55, P473

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CHIANG, LY ;

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[3] NOVEL ORGANIC POLYMER-FILMS WITH HIGH INTRINSIC CONDUCTIVITY DERIVED FROM THE VAPOR-PHASE THERMOLYSIS OF POLYQUINOLINE [J].

CHIANG, LY .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :304-305

[4]

DENISEVICH P, 1983, POLYM PREPR-ACS, V24, P330

[5] MOLYBDENUM AND RHENIUM COMPLEXES OF AROMATIC AMINE THIOLATE LIGANDS [J].

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INORGANIC CHEMISTRY, 1978, 17 (04) :897-904

[6] CONDUCTING POLYQUINOLINES [J].

TUNNEY, SE ;

SUENAGA, J ;

STILLE, JK .

MACROMOLECULES, 1983, 16 (08) :1398-1399

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