A LASER FLASH-PHOTOLYSIS STUDY OF ELECTRON-TRANSFER PROCESSES OF [RU(BPY)(3)](2+) IN HIGH MAGNETIC-FIELD

被引：10

作者：

MUKAI, M ^{[1
]}

TANAKA, H ^{[1
]}

FUJIWARA, Y ^{[1
]}

TANIMOTO, Y ^{[1
]}

机构：

[1] HIROSHIMA UNIV, FAC SCI, DEPT CHEM, HIGASHIHIROSHIMA 724, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 11期

关键词：

D O I：

10.1246/bcsj.67.3112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of high magnetic fields (less than or equal to 13 T) on the charge transfer reaction between Ru(II) tris(2,2'-bipyridine) and methylviologen is studied by laser hash photolysis in a pulse magnet. The initial yield of the methylviologen radical decreases by about 20% at 13 T and the second order decay rate constant of the escaped radicals increases as the magnetic field increases. These effects of high magnetic field are interpreted in terms of the Delta g mechanism with strong spin-orbit coupling proposed by Steiner et al.

引用

页码：3112 / 3115

页数：4

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