SUBSTITUTED POLYTHIOPHENES - EFFECT OF SUBSTITUENT AND REGIOCHEMISTRY ON PHYSICAL-PROPERTIES

被引：32

作者：

MURRAY, KA ^{[1
]}

MORATTI, SC ^{[1
]}

BAIGENT, DR ^{[1
]}

GREENHAM, NC ^{[1
]}

PICHLER, K ^{[1
]}

HOLMES, AB ^{[1
]}

FRIEND, RH ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CAVENDISH LAB,DEPT PHYS,CAMBRIDGE CB3 0HE,ENGLAND

来源：

SYNTHETIC METALS | 1995年 / 69卷 / 1-3期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0379-6779(94)02503-Q

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A substituted head-to-tail polythiophene random copolymer containing alkyl and omega-hydroxyalkyl side chains has been synthesised by nickel-mediated cross-coupling of well-defined Grignard precursors. The omega-hydroxyl group is protected during polymerisation as a tetrahydropyranyl (THP) ether which is removed afterwards to give the free alcohol. The regioregular poly(3-alkylthiophenes) with hexyl or dodecyl side chains have also been synthesised and their physical and fluorescence emission properties investigated.

引用

页码：395 / 396

页数：2

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