CHEMISTRY OF CYCLOPROPANOLS .7. PYROLYSIS OF CYCLOPROPYL ACETATES

被引：8

作者：

DEPUY, CH

ZABEL, DE

WIEDEMAN, W

机构：

[1] Department of Chemistry, University of Colorado, Boulder

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 06期

关键词：

D O I：

10.1021/jo01270a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On pyrolysis at 485° cyclopropyl acetate, 1-methylcyclopropyl acetate, and 1,2,2-trimethylcyclopropyl acetate undergo a smooth rearrangement to allylacetates or their pyrolysis products. 1- and 2-arylcyclopropyl acetates, by contrast, give rise to numerous products including methylphenylacetylene, propiophenone, and indene derivatives. The products of both groups of compounds are suggested to arise by cyclopropane-bond homolysis. © 1968, American Chemical Society. All rights reserved.

引用

页码：2198 / &

共 15 条

[1] PYROLYSIS OF ESTERS .10. MECHANISM OF 1,4-ELIMINATION [J].