PHASE-EQUILIBRIA IN SO2+H2O - SULFUR-DIOXIDE GAS HYDRATE, 2 LIQUID-PHASES, AND THE GAS-PHASE IN THE TEMPERATURE-RANGE 273-K TO 400-K AND AT PRESSURES UP TO 400-MPA

被引：29

作者：

VANBERKUM, JG

DIEPEN, GAM

机构：

[1] Delft University of Technology, Department of Chemistry, 2628 BL Delft

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1979年 / 11卷 / 04期

关键词：

D O I：

10.1016/0021-9614(79)90053-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The H + L1 + L2 phase relations, where L1 and L2 stand for the liquid phases rich in hydrate former (sulfur dioxide) and water respectively and H for the gas hydrate, in sulfur dioxide + water have been investigated in the pressure range 1 to 400 MPa. The threephase line shows a maximum temperature at (293.68 ± 0.1) K at (3072 ± 20) atm. It can be concluded that the system shows a congruent melting line of the gas hydrate from (2100 ± 10) atm, up to higher pressures showing a temperature maximum at (294.05 ± 0.05) K and (3450 ± 20) atm. The critical mixing curve L1 = L2 has been partly determined. From the experimental results it is not certain whether or not this curve shows a temperature minimum. In addition the L1 + L2 + G relations in the temperature range 285 to 395 K have been investigated. Finally the solubility of sulfur dioxide in liquid water as a function of temperature has been determined in the presence of the second liquid and gas. © 1979.

引用

页码：317 / 334

页数：18

共 19 条

[1]

Aaldijk L., 1971, THESIS DELFT U TECHN

[2]

BAKHUISROOZEBOO.HW, 1918, HETEROGENE GLEICHGEW, V2, P193

[3]

BAKHUISROOZEBOO.HW, 1884, REC TRAV CHIM, V3, P42

[4]

BAKHUISROOZEBOO.HW, 1918, HETEROGENE GLEICHGEW, V2, P42

[5]

BORSEKEN AM, 1919, VERSLAG AKAD WET, V27, P1104

[6]

FRIEDRICHS KF, 1913, J AM CHEM SOC, V35, P1866

[7]

FRIEDRICHS KF, 1913, Z ANORG ALLG CHEM, V84, P373

[8] THE DETERMINATION AND THE SOLUBILITY OF WATER IN LIQUID SULFUR DIOXIDE [J].

MURAKAMI, D ;

TOKURA, N .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1958, 31 (04) :431-434

[9]

OSTWALD WZ, 1888, PHYS CHEM, V1, P204

[10]

PIERRE L, 1888, ANN CHIM PHYS, V23, P416

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