STEREOSELECTIVE CONSTRUCTION OF QUATERNARY CARBONS BY THE REACTION OF ALDEHYDES WITH ALLYLIC CHROMIUM REAGENTS PREPARED FROM 1,3-DIENE MONOEPOXIDES AND CRCL2

被引：32

作者：

FUJIMURA, O ^{[1
]}

TAKAI, K ^{[1
]}

UTIMOTO, K ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,KYOTO 606,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 06期

关键词：

D O I：

10.1021/jo00293a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A vinyl-substituted (3-hydroxy carbanion syn-thon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of Lil. The reagent reacts with aldehydes to afford R*,R* adducts stereoselectively. © 1990, American Chemical Society. All rights reserved.

引用

页码：1705 / 1706

页数：2

共 34 条

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