SOLVENT-EXTRACTION OF PHTHALATE ISOMER DIANIONS BY THE USE OF DICATIONIC ANION-EXCHANGE EXTRACTANTS

The extraction of phthalate isomer dianions (phthalate, isophthalate and terephthalate) was studied by the use of dicationic anion-exchange extractants, polymethylenebis(trioctylphosphonium)s (abbreviated as CnBP). Extraction equilibrium studies confirmed that the extraction reaction of phthalate isomers under high pH condition (pH>11) occurs via the formation of a 1:1 ion-pair complex between CnBP and the phthalate isomer. The extraction ability of dicationic extractants was greatly superior to that of conventional monocationic extractants. Further, the extraction ability of dicationic extractants was dependent on the length of the bridging methylene-chain between two phosphonium cationic centers within the extractants. In the extractions of phthalate, isophthalate and terephthalate, the most favorable extractants were C4BP, C6BP and C8BP, respectively. Thus, since the distance between the two anionic centers of phthalate isomer is longer, the bridge-chain length of the most preferable extractant is longer. © 1990, The Japan Society for Analytical Chemistry. All rights reserved.