SYNTHESIS, STRUCTURE AND RESOLUTION OF A DINUCLEAR CO-III TRIPLE-HELIX

被引：95

作者：

CHARBONNIERE, LJ

BERNARDINELLI, G

PIGUET, C

SARGESON, AM

WILLIAMS, AF

机构：

[1] UNIV GENEVA,DEPT INORGAN ANALYT & APPL CHEM,CH-1211 GENEVA 4,SWITZERLAND

[2] UNIV GENEVA,XRAY CRYSTALLOG LAB,GENEVA,SWITZERLAND

[3] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 2600,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001419

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time a helical dinuclear metal complex has been separated into enantiomers by transformation of a labile cobalt(ii) triple-helical complex into the kinetically stable cobalt(iir) complex [CO2(2a)(3)](6+) which has been characterized structurally and resolved by chromatography.

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页码：1419 / 1420

页数：2

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