AN UNEXPECTED MOLYBDENUM(0) COMPLEX WITH MOP6 COORDINATION - CRYSTAL-STRUCTURE OF [MO(P(CH2CH2PPH2)3)2] C5H10

被引:10
作者
GARCIABASALLOTE, M
VALERGA, P
PUERTAVIZCAINO, MC
ROMERO, A
VEGAS, A
MARTINEZRIPOLL, M
机构
[1] UNIV CADIZ,FAC CIENCIAS,DEPT QUIM INORGAN,E-11510 PUERTO REAL,SPAIN
[2] CSIC,INST ROCASOLANO,UEI CRISTALOG,E-28006 MADRID,SPAIN
关键词
D O I
10.1016/0022-328X(91)86465-3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of trans-[Mo(N2)2(PPh2Me)4] with the tripodal phosphine tris(2-diphenylphosphinoethyl)phosphine, PP3, in benzene has been studied. The product was recrystallized from a mixture of benzene and petroleum ether to give [Mo(PP3)2].C5H10, whose crystal structure shows a distorted octahedral ''MoP6'' coordination with both phosphines acting as tridentate ligands.
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页码:371 / 377
页数:7
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