PRODUCTION OF C-60 RADICAL CATION BY PHOTOSENSITIZED ELECTRON-TRANSFER

被引：124

作者：

NONELL, S ^{[1
]}

ARBOGAST, JW ^{[1
]}

FOOTE, CS ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 11期

关键词：

D O I：

10.1021/j100190a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The radical cation of C60 is prepared by electron transfer to singlet N-methylacridinium hexafluorophosphate. It has lambda(max) near 980 nm. The radical cation can also be prepared in higher yield by cosensitization, using high concentrations of biphenyl to form biphenyl radical cation which is the ultimate oxidant for C60.

引用

页码：4169 / 4170

页数：2

共 26 条

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