CRYSTAL-STRUCTURE OF [CP(ASTERISK)BBR][ALBR4]

被引：20

作者：

DOHMEIER, C

KOPPE, R

ROBL, C

SCHNOCKEL, H

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSRUHE,GERMANY

[2] UNIV JENA,INST ANORGAN & ANALYT CHEM,D-07743 JENA,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

X-RAY STRUCTURE; AB INITIO; BORON; BROMIDE; CYCLOPENTADIENYL; GROUP B;

D O I：

10.1016/0022-328X(94)05089-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The spectroscopic characterization of the cation [Cp*BBr](+) from 1979 is now followed by its structural determination with the help of X-ray methods. The B-C-distance with 168 pm is in the same range as that of carboranes. The methyl groups of the Cp*-ring are bent in the direction of the boron atom.

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页码：127 / 130

页数：4

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